| Identification | Back Directory | [Name]
Tetrakis(4-aminophenyl)methane | [CAS]
60532-63-0 | [Synonyms]
Tetra(4-anilyl)methane
Tetra(4-aminophenyl)methane
Tetrakis(4-aminophenyl)methane
Tetrakis(4-aminophenyl)methane 95%
4-[tris(4-aminophenyl)methyl]aniline
4,4',4'',4'''-methanetetrayltetraaniline
Tetrakis(4-aminophenyl)methane AldrichCPR
4-(tris-(4-aminophenyl)methyl)Benzenamine
Benzenamine, 4,4',4'',4'''-methanetetrayltetrakis-
Tetrakis(4-aminophenyl)methane ISO 9001：2015 REACH | [Molecular Formula]
C25H24N4 | [MDL Number]
MFCD12546930 | [MOL File]
60532-63-0.mol | [Molecular Weight]
380.485 |
| Chemical Properties | Back Directory | [Melting point ]
320°C(dec.)(lit.) | [Boiling point ]
639.7±55.0 °C(Predicted) | [density ]
1.247±0.06 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
powder | [pka]
5.75±0.25(Predicted) | [color ]
White to Orange to Green | [InChIKey]
LNHGLSRCOBIHNV-UHFFFAOYSA-N | [CAS DataBase Reference]
60532-63-0 |
| Hazard Information | Back Directory | [Uses]
Tetrakis(4-aminophenyl)methane can be used as a synthetic material intermediate. It can also be used to synthesize the structurally similar COF-320, which differs from COF-300 by the length of the linear dialdehyde linker, employing 4-4’-biphenyldicarboxyaldehyde instead of terephthalaldehyde. Lastly, a tetrahedral aldehyde monomer, tetrakis(4-formylphenyl)methane, is synthesized and used alongside tetrakis(4-aminophenyl)methane to explore the synthesis of a novel tetraaminetetraaldehyde COF. | [Preparation]
synthesis of Tetrakis(4-aminophenyl)methane: Tetrakis-(4-nitrophenyl)methane (1.5 g, 3 mmol) was dissolved in tetrahydrofuran (100 ml), and Raney nickel (10 g) was added to the solution while stirring under nitrogen. Hydrazine monohydrate (2 g, 0.04 mol) was slowly added via syringe, and the mixture was refluxed for 4 h. The mixture was filtered while hot and washed with ethanol. The filtrate was dried in vacuo. The crude product was subsequently washed with ethanol (50 ml) and dried in vacuo to afford Tetrakis(4-aminophenyl)methane as a white solid (0.92 g, 81% yield).
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