Identification | Back Directory | [Name]
(+)-CAMPHENE | [CAS]
5794-03-6 | [Synonyms]
C06304 FEMA 2229 d-Camphene Camphene, (1R,4S)-(+)- (+)-CAMPHENE 80+% FCC (+)-CAMPHENE, TECH., 80% (+)-CAMPHENE ISO 9001:2015 REACH (+)-Camphene technical grade, 80% 2,2-Dimethyl-3-methylenenorborhane (1R,4S)-2,2-dimethyl-3-methylene-norbornane 2,2-dimethyl-3-methylene-,(1R)-Bicyclo[2.2.1]heptane 2-dimethyl-3-methylene-(1theta)-bicyclo[2.2.1]heptan (1α,4α)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane (1β,4β)-2-Methylene-3,3-dimethylbicyclo[2.2.1]heptane (1R,4S)-6,6-dimethyl-5-methylidenebicyclo[2.2.1]heptane (1S,4R)-3,3-dimethyl-2-methylidenebicyclo[2.2.1]heptane (1R,4S)-6,6-dimethyl-5-methylidene-bicyclo[2.2.1]heptane Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1R,4S)- [1R,4S,(+)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane (+)-Camphene,(1R)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane | [EINECS(EC#)]
227-336-2 | [Molecular Formula]
C10H16 | [MDL Number]
MFCD00003756 | [MOL File]
5794-03-6.mol | [Molecular Weight]
136.23 |
Chemical Properties | Back Directory | [Melting point ]
40-50 °C(lit.) | [Boiling point ]
159-160 °C(lit.) | [density ]
0.839 g/mL at 25 °C(lit.) | [refractive index ]
1.4562 (estimate) | [Fp ]
98 °F | [solubility ]
Benzene (Slightly), Chloroform (Slightly), | [form ]
Solid | [color ]
White to Off-White Waxy | [Odor]
at 10.00 % in dipropylene glycol. fresh herbal woody fir camphor | [Odor Type]
woody | [optical activity]
[α]20/D +16°, c = 4 in ethanol | [LogP]
4.220 | [EPA Substance Registry System]
Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1R,4S)- (5794-03-6) |
Hazard Information | Back Directory | [Physical properties]
Camphene is a colorless, crumbly crystalline
solid with a camphor-like odor. It has a tendency
to sublime. | [Uses]
(+)-Camphene is part of a mixture which is responsible for the anti-inflammatory effect of essential oil from Citrus aurantium L. var. amara Engl. | [Definition]
ChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has R configuration at position 1 and S configuration at position 4. | [Production Methods]
The extraction of camphene by distillation of
turpentine is now hardly used in industry. Instead camphene is produced from a-pinene. | [Chemical Reactivity]
Camphene is stable in air and light. At elevated temperatures, in the presence of oxygen, it undergoes autoxidation to camphenilone. Peracids attack the double bond, giving camphene oxide. Catalytic hydrogenation gives the saturated hydrocarbon isocamphane.
| [Biochem/physiol Actions]
Taste at 100 ppm |
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