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ChemicalBook--->CAS DataBase List--->494227-36-0

494227-36-0

494227-36-0 Structure

494227-36-0 Structure
IdentificationBack Directory
[Name]

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
[CAS]

494227-36-0
[Synonyms]

MANDYPHOS SL-M003-1
(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phos
(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-,2'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}ferrocene
(SP,SμP)-1,1μ-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene
(R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE
(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
(S,S)-(-)-2,2'-Bis[(R)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis[di(3,5-trifluoroMethylphenyl)phosphino]ferrocene
(S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINO]FERROCENE
(S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-trifluoromethylphenyl)phosphino)ferrocene
(aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di(bis-(3,5-trifluoromethyl)phenyl)-phosphino]ferrocene
(r,r)-1,1'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2'-bis[(r)-α-(dimethylamino)benzyl]ferrocene (acc to cas)
(aR,aR)-2,2'-Bis(a-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis[di-(bis(3,5-trifluoromethyl)-phenyl)phosphino]-ferrocene
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene,min.97%
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene, min. 97%
Mandyphos SL-M003-1, (1R,1μR)-1,1μ-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)
[Molecular Formula]

C60H42F24FeN2P2 10*
[MDL Number]

MFCD04117703
[MOL File]

494227-36-0.mol
[Molecular Weight]

1364.74
Chemical PropertiesBack Directory
[alpha ]

-250.2° (c 1.0, CHCl3)
[form ]

solid
[color ]

orange-red
[Stability:]

store cold
Hazard InformationBack Directory
[Chemical Properties]

Orange powder
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[HS Code ]

29319090
Questions And AnswerBack Directory
[Reaction]

  1. Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
  2. Ligand for Rh-catalyzed hydrogenation of αand β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3diketones.
  3. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
  4. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
  5. Ligand for Cu-catalyzed enantioselective hydroboration of αand β-unsaturated esters and nitriles.
Reactions of 494227-36-0
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