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ChemicalBook--->CAS DataBase List--->4430-18-6

4430-18-6

4430-18-6 Structure

4430-18-6 Structure
IdentificationBack Directory
[Name]

ACID VIOLET 43
[CAS]

4430-18-6
[Synonyms]

CI 60730
Violet 43
CI NO 60730
MURASAKI401
EXT. VIOLET 2
SOLWAY PURPLE
ACID VIOLET 43
Acid Violet 3B
EXT.D&CVIOLET2
SOLWAY PURPLE R
C.I.ACIDVIOLET43
Egacid Violet 3B
QUINIZARIN BLUE R
Ext.D&Cvioletno.2
JAROCOL VIOLET 43
Aminyl Violet E-3B
Alizarine Irisol R
Alizarin violet 3B
Brilliant Violet R
ANTHRAQUINONE IRIS R
Ext.D and C Violet No.2
Triacid Light Violet 3B.
Suminol Levelling Violet 3B
Acid violet 43 (C.I. 60730)
Hastings Light Fast Violet IRS
6-((4-HYDROXY-1-ANTHRAQUINONYL)AMINO)-META-TOLUENESULFONIC ACID, MONOSODIUM SALT)
sodium 4-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anthryl)amino]toluene-3-sulphonate
2-[(9,10-Dihydro-9,10-dioxo-4-hydroxyanthracen-1-yl)amino]-5-methylbenzenesulfonic acid sodium salt
Monosidiumsaltof2-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anteracenyl)amino]-5-methyl-benzenesulfonicacid
Benzenesulfonic acid, 2-(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anthracenyl)amino-5-methyl-, monosodium salt
Benzenesulfonic acid,2-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anthracenyl)aMino]-5-Methyl-, sodiuMsalt (1:1)
Monosidium salt of 2-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anteracenyl)amino]-5-methyl-benzenesulfonic acid
Benzenesulfonic acid 2-[(9, 10-dihydro-4-hydroxy-9, 10-dioxo-1-anthracenyl) aminol-5-methyl], monosodium salt
acid violet 43 Monosidium salt of 2-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-anteracenyl) amino]-5-methyl-benzenesulfonic acid
[EINECS(EC#)]

224-618-7
[Molecular Formula]

C21H14NNaO6S
[MDL Number]

MFCD00068446
[MOL File]

4430-18-6.mol
[Molecular Weight]

431.39
Chemical PropertiesBack Directory
[density ]

0.513[at 20℃]
[vapor pressure ]

0.072Pa
[storage temp. ]

Hygroscopic, -20°C Freezer, Under inert atmosphere
[solubility ]

Methanol (Slightly), Water (Slightly)
[Colour Index ]

60730
[form ]

Solid
[color ]

Dark Purple to Black
[Water Solubility ]

1.708-50.3g/L at 20-28℃
[Stability:]

Stable for 4 hours in acetone/olive oil (6.05 and 151 mg active dye/ml) and purified water (3.03 and 121 mg active dye/ml) at room temperature, protected from light and under inert gas atmosphere. Deviation from initial value was between – 4 % and 6 % after 4 hours (only tested for Jarocol Violet 43, Batch No. 10130)
[InChIKey]

GTKIEPUIFBBXJQ-UHFFFAOYSA-M
[EPA Substance Registry System]

C.I. Acid Violet 43 (4430-18-6)
Safety DataBack Directory
[Risk Statements ]

36
[Safety Statements ]

24/25
[HS Code ]

32041200
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1,4-Dihydroxyanthraquinone-->1-bromo-4-hydroxyanthraquinone-->1,4-Dihydroxyanthraquinone-->p-Toluidine-->1-chloro-4-hydroxyanthraquinone
Hazard InformationBack Directory
[Description]

Acid Violet 43 is an anthraquinone color that functions as a colorant in cosmetic formulations (Wenninger, Canterbery, and McEwen 2000). Batches of Acid Violet 43 that are certified by the Food and Drug Administration (FDA) as meeting the standards and specifications described in the Code of Federal Regulations (21 CFR 73 & 74) are named Ext. D & C Violet No. 2 (FDA 1976). Most of the available safety test data are from studies of Ext. D & C Violet No. 2 conducted to support FDA listing this color for drug and cosmetic use.
[Physical properties]

Acid Violet 43 has a bluish violet hue in daylight and is slightly redder in artificial light (tungsten) (Society of Dyers and Colourists 1971a). It is soluble in alcohol (Society of Dyers and Colourists 1971b) and water (Hazleton Laboratories, Inc. 1968). It is blue in concentrated sulfuric acid, olive-brown after dilution, accompanied by a purple precipitate.
[Uses]

Acid Violet 43 is an anthraquinone colour used in semi-permanent hair dye formulations at a maximum concentration of 0.5% active dye. According to the EU Cosmetics Directive 76/768/EEC, Annex IV Part I List of Colouring Agents, Acid Violet 43 is allowed as CI 60730 in cosmetic products except those intended to come into contact with mucous membranes.
[Preparation]

Will be 1,4-Dihydroxyanthracene-9,10-dione or anthracene-1,4,9,10-tetraol?or 1-Bromo-4-hydroxyanthraquinone?(or?1-Chloro-4-hydroxyanthracene-9,10-dione) and reaction p-Methylaniline, then stlfonation, and translated into sodium salt.
[Flammability and Explosibility]

Nonflammable
[Industrial uses]

Acid violet 43 is used for the dyeing of wool and its products. It can be used for dyeing and printing of wool, silk, nylon and its fabrics, as well as for leather dyeing.
[Safety]

In 2001, the Cosmetic Ingredient Review (CIR) Expert Panel (Panel) published a safety assessment with the conclusion that Acid Violet 43 is safe for use in hair dye formulations when free of impurities except for the following: ≤18% volatile matter (at 135°C) and chlorides and sulfates (calculated as sodium salts); ≤0.4% water-insoluble matter; ≤0.2% 1-hydroxy-9,10-anthracenedione; ≤0.2% 1,4-dihydroxy-9,10-anthracenedione; ≤0.1% p-toluidine; ≤0.2% p-toluidine sulfonic acids, sodium salts; ≤1% subsidiary colors; ≤20 ppm lead (as Pb); ≤3 ppm arsenic (as As); ≤1 ppm mercury as (Hg); and ≥80% total color.
Amended Safety Assessment of Acid Violet 43 as Used in Cosmetics
[Properties and Applications]

blue purple. Soluble in alcohol. The strong sulfuric acid in blue, diluted for olive brown, then a purple precipitation.
Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO 5 1-2 1-2 3-4 1 5 2 1
AATCC 3 1 1 2 1 1 2 2
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