| Identification | Back Directory | [Name]
pelletierine | [CAS]
4396-01-4 | [Synonyms]
pelletierine
isopelletierine
1-piperidin-2-ylacetone
1-(2-Piperidinyl)acetone
2-(2-Oxopropyl)piperidine
1-(2-Piperidyl)-2-propanone
1-piperidin-2-ylpropan-2-one
1-(2-Piperidinyl)-2-propanone
2-Propanone, 1-(2-piperidinyl)-
1-piperidin-2-ylacetone (SALTDATA: FREE)
1-piperidin-2-ylacetone(SALTDATA: 0.15H2O)
1-Piperidin-2-ylacetone
DISCONTINUED. Please see B449984.
2-Acetonylpiperidinepunicineisopelletierine, (.+/-.)-pelletierine | [EINECS(EC#)]
224-523-0 | [Molecular Formula]
C8H15NO | [MDL Number]
MFCD01459222 | [MOL File]
4396-01-4.mol | [Molecular Weight]
141.21 |
| Chemical Properties | Back Directory | [Melting point ]
130-132 °C | [Boiling point ]
195 °C | [density ]
0.918±0.06 g/cm3(Predicted) | [storage temp. ]
Hygroscopic, -20°C Freezer, Under inert atmosphere | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
Oil | [pka]
pK1:9.45 (15°C) | [color ]
Colourless to Light Yellow | [Stability:]
Hygroscopic |
| Hazard Information | Back Directory | [Description]
An alkaloid of this name was discovered by Tanret but when this alkaloid was
shown to be (±)-pelletierine, the name was adopted for this particular base
isolated from Punica granatum. The alkaloid is an oily liquid which yields a
number of well crystalline salts and derivative: the hydrochloride, m.p. 143°C;
hydrobromide, m.p. 149°C; picrate, m.p. 147 -8°C and the picrolonate, m.p. 185-6°C. The N-acetyl derivative is an oily liquid, b.p. 110-5°C/0.I mm while
the N-benzoyl compound is crystalline with m.p. 72-4°C. The alkaloid may be
prepared by the demethylation of methylisopelletierine, the action being revers_x0002_ible. | [Definition]
ChEBI: Pelletierine is a citraconoyl group. | [References]
Tanret., Compt. rend., 88, 716 (1879)
Tanret., ibid, 90, 696 (1880)
Hesse., Rev. trav. Chim., 52, 1005 (1919)
Hess, Littman., Annalen, 494, 7 (1932)
Wibaut, Kloppenburg, Beets., Rev. trav. Chim., 63, 134 (1944)
Anet, Hughes, Ritchie., Nature, 164, 50 I (1949)
Galinovsky, Branchetti, Vogl.,Monatsh., 84, 1221 (1953)
Galinovsky, Hollinger., ibid, 85, 1012 (1954)
Wibaut, Hirschel., Rev. trav. Chim., 75,225 (1956) |
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