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ChemicalBook--->CAS DataBase List--->435293-93-9

435293-93-9

435293-93-9 Structure

435293-93-9 Structure
IdentificationBack Directory
[Name]

Ir(piq)3, Tris[1-phenylisoquinolinato-C2,N]iridium(III)
[CAS]

435293-93-9
[Synonyms]

(piq)3Ir
Tris(1-phenylisoquinoline)iridium
tris(2-(isoquinolin-1-yl)phenyl)iridium
Tris[1-phenylisoquinoline-C2,N]iridium(Ⅲ)
Tris[1-phenylisoquinoline-C2,N]iridium(III)
Tris[1-phenylisoquinolinato-C2,N]iridiuM(III)
Ir(piq)3 , Tris(1-phenylisoquinoline) iridiuM(III)
Tris(1-phenylisoquinoline-C2,N)iridium(III), Ir(piq)3
Ir(piq)3, Tris[1-phenylisoquinolito-C2,N]iridium(III)
Tris[1-phenylisoquinoline-C2,N]iridiuM(III)
Ir(piq)3, Tris[1-phenylisoquinolinato-C2,N]iridium(III)
Iridium,tris[2-(1-isoquinolinyl-kN)phenyl-kC]-,(OC-6-22)-
Tris[1-phenylisoquinoline-C2,N]iridium(III) (purified by sublimation)
Bis(4,4'-difluorol-2,3-diphenylquinoxaline-C2,N)(acetylacetonate)iridium(III)
[Molecular Formula]

C45H30IrN3
[MDL Number]

MFCD09842770
[MOL File]

435293-93-9.mol
[Molecular Weight]

804.973
Chemical PropertiesBack Directory
[Melting point ]

454 °C
[InChIKey]

DGLAKLWHAUIQCS-UHFFFAOYSA-N
[Absorption]

λmax 324 nm in THF
[Odor]

Dark-red powder
Hazard InformationBack Directory
[Chemical Properties]

Yellow to dark red solid
[Uses]

suzuki reaction
[Description]

Tris(1-phenylisoquinoline)iridium(III), Ir(piq)3 is a deep red phosphorescent dopant material.
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

28439000
Questions And AnswerBack Directory
[Classification]

Organometallic iridium complex, Red emitter, Phosphorescence dopant OLEDs, Sublimed materials.
[Applications]

Tris(1-phenylisoquinoline)iridium(III), Ir(piq)3 is a deep red phosphorescent dopant material.
Due to their high electron affinities, quinoline/isoquinoline-based compounds have received considerable attention in optoelectronic materials. With greater π-electronic conjugation in the isoquinoline ring, the energy of the lowest unoccupied molecular orbital (LUMO) is significantly lowered, and the energy gap is reduced.
Ir(piq)3, together with Ir(piq)2acac, are the ones that have been most studied in theisoquinoline iridium complex family. The 'piq' unit of the ligand part can partially suppress the triplet-triplet annihilation and show short phosphorescent lifetimes.
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