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ChemicalBook--->CAS DataBase List--->42152-46-5

42152-46-5

42152-46-5 Structure

42152-46-5 Structure
IdentificationBack Directory
[Name]

COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
[CAS]

42152-46-5
[Synonyms]

COPPER(I) TRIFLATE BENZENE COMPLEX
Trifluoromethanesulfonic acid, copper(I) salt
COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
Cuprous trifluoromethanesulfonate benzene complex
Copper(I) trifluoromethanesulfonate benzene complex,90%
Trifluoromethanesulfonicacidcopper(1)saltbenzenecomplex
Copper (I) trifluoroMethanesulfonate benzene coMplex 90%
Copper(I) trifluoromethanesulfonate benzene complex ,88%
BIS[COPPER (I) TRIFLUOROMETHANESULFONATE], BENZENE COMPLEX
TRIFLUOROMETHANESULFONIC ACID COPPER(I) SALT BENZENE COMPLEX
Copper(I) trifluoroMethanesulfonate benzene coMplex, 90% 1GR
Copper(I) trifluoroMethanesulfonate benzene coMplex, 90% 5GR
copper trifluoromethanesulphonate, compound with benzene (2:1)
COPPER(I) TRIFLUOROMETHANESULFONATE BENZ ENE COMPLEX, TECH., 90%
Copper(I) trifluoroMethanesulfonate benzene coMplex technical grade, 90%
Methanesulfonic acid, trifluoro-, copper(1+) salt, compd. with benzene (2:1)
Copper(I) Triflate Benzene Complex Trifluoromethanesulfonic Acid Copper(I) Salt Benzene Complex
Copper(I) triflate benzene complex, Cuprous trifluoromethanesulfonate benzene complex, Trifluoromethanesulfonic acid copper(I) salt benzene complex
Copper(I) trifluoromethanesulfonate benzene complex,Copper(I) triflate benzene complex, Cuprous trifluoromethanesulfonate benzene complex, Trifluoromethanesulfonic acid copper(I) salt benzene complex
[EINECS(EC#)]

255-686-6
[Molecular Formula]

C8H6Cu2F6O6S2
[MDL Number]

MFCD00043300
[MOL File]

42152-46-5.mol
[Molecular Weight]

503.34
Chemical PropertiesBack Directory
[Appearance]

Grey-greenish powder
[Melting point ]

160 °C (dec.)(lit.)
[Fp ]

45 °F
[storage temp. ]

Refrigerator
[form ]

Powder
[color ]

Gray-greenish
[InChIKey]

OGHGYDFTMBZZJU-UHFFFAOYSA-M
[CAS DataBase Reference]

42152-46-5
Hazard InformationBack Directory
[Chemical Properties]

Grey-greenish powder
[Uses]

Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst:
  • To synthesize enol-esters via copper(I) carboxylate intermediate formation.
  • In the enantioselective allylic oxidation of cyclic alkenes.
  • To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation.

It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.
Safety DataBack Directory
[Hazard Codes ]

F
[Risk Statements ]

11-36/37/38
[Safety Statements ]

16-26-36
[RIDADR ]

UN 3175 4.1/PG 2
[WGK Germany ]

3
[HazardClass ]

4.1
[PackingGroup ]

II
[HS Code ]

29049090
Spectrum DetailBack Directory
[Spectrum Detail]

COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX(42152-46-5)IR
COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX(42152-46-5)FT-IR
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