| Identification | Back Directory | [Name]
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT | [CAS]
415918-91-1 | [Synonyms]
(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine
(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′
]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f]
[1,3,2]dioxaphosphepin-4-amine
R-(3,5-Dioxa-4-Phospha-Cyclohepta[2,1-A:3,4-A']Dinaphthalen-4-yl)Bis[(1R)-1-Phenylethyl]aMine
(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS)
(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f]
[1,3,2]dioxaphosphepin-4-amine,99%e.e.
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% | [Molecular Formula]
C37H32Cl2NO2P | [MDL Number]
MFCD04117687 | [MOL File]
415918-91-1.mol | [Molecular Weight]
624.54 |
| Chemical Properties | Back Directory | [Melting point ]
102-103 °C
| [alpha ]
+427° (c 0.83, CHCl3) | [Boiling point ]
710.7±63.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Powder | [pka]
-0.57±0.20(Predicted) | [color ]
white | [Sensitive ]
moisture sensitive | [CAS DataBase Reference]
415918-91-1 |
| Questions And Answer | Back Directory | [Reactions]
- A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
- Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
- allylic esters.
- Asymmetric hydrogenation.
- Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
- Asymmetric hydrovinylation.
- Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
- Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
- Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
- Palladium-catalyzed enantioselective diamination of alkyl dienes.
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| Hazard Information | Back Directory | [Uses]
(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles. |
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| Company Name: |
Energy Chemical
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| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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