| Identification | Back Directory | [Name]
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL | [CAS]
38345-66-3 | [Synonyms]
chirald
Oxiphene
CHIRALD(R)
chirald tm
D-OXYPHENE
DEXTROOXYPHENE
α-(+)-Oxyphene
Darvon alcohol
Einecs 253-893-6
Mosher'S reagent
DEXTROCARBINOL BASE
(2S,3R)-4-(Dimethylamino)-1,2-diphe
2-S-3-R-plus-4-dimethylamino-1-2-*diphenyl-3-meth
(2S,3R)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
(2S,3R)-4-(dimethylamino)-3-methyl-1,2-diphenylbutan-2-ol
(2S,3R)-1,2-Diphenyl-3-methyl-4-(dimethylamino)-2-butanol
(+)-(2S,3R)-4-DIMETHYLAMINO-3-METHYL-1,2-DIPHENYL-2-BUTANOL
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
(αS)-α-Phenyl-α-[(R)-1-(dimethylaminomethyl)ethyl]benzeneethanol
(αS)-α-[(1R)-2-(Dimethylamino)-1-methylethyl]-α-phenylbenzeneethanol
Benzeneethanol, α-[(1R)-2-(dimethylamino)-1-methylethyl]-α-phenyl-, (αS)-
(2S,3R)-4-(DIMETHYLAMINO)-3-METHYL-1,2-DIPHENYLBUTAN-2-OL, TOLUENE SOLUTION
[S-(R*,S*)]-alpha-[2-(dimethylamino)-1-methylethyl]-alpha-phenylphenethyl alcohol
Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol
(2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol, Dextrocarbinol base
Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol | [EINECS(EC#)]
253-893-6 | [Molecular Formula]
C19H25NO | [MDL Number]
MFCD00066214 | [MOL File]
38345-66-3.mol | [Molecular Weight]
283.41 |
| Hazard Information | Back Directory | [Uses]
Reducing reagent in organic synthesis. | [Purification Methods]
Purify the hydrochloride by dissolving 1.5g in 13.5 mL of 5N HCl, heat to boiling and evaporate in a vacuum. Recrystallise the hydrochloride three times from MeOH/EtOAc giving m 189-190o, []D -33.7o (c 1, H2O) {enantiomer has +34.2o}. The hydrochloride in the minimum volume of water is basified with aqueous 5N NaOH and extracted with Et2O. The extract is dried (K2CO3) and evaporated, leaving a residue which is stored in a desiccator over solid KOH as a low melting solid. It can be recovered using these procedures from asymmetric reductions with LAH, and re-used. [Pohland & Sullivan J Am Chem Soc 77 3400 1955, Sullivan et al. J Org Chem 28 2483 1963, Beilstein 13 IV 2221.] |
| Spectrum Detail | Back Directory | [Spectrum Detail]
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)MS
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)1HNMR
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)IR1
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)IR2
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL(38345-66-3)Raman
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