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ChemicalBook--->CAS DataBase List--->33396-29-1

33396-29-1

33396-29-1 Structure

33396-29-1 Structure
IdentificationBack Directory
[Name]

Erythromycin A Enol Ether
[CAS]

33396-29-1
[Synonyms]

EM 523
Erythromycin impurity B
Erythromycin A Enol Ether
9-Deoxo-6-deoxy-6,9-epoxy-8,9-didehydroerythromycin
6,9-Epoxy-8,9-didehydro-9-deoxo-6-deoxyerythromycin
6-Deoxy-9-deoxo-8,9-didehydro-6,9-epoxyerythromycin
6β,9-Epoxy-8,9-didehydro-9-deoxo-6-deoxyerythromycin
(6R)-6-Deoxy-9-deoxo-6,9-epoxy-8,9-didehydroerythromycin
11-(4-Dimethylamino-3-hydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-5-ethyl-3,4-dihydroxy-9-(5-hydroxy-4-methoxy-4,6-dimethyl-tetrahydro-pyran-2-yloxy)-2,4,8,10,12,14-hexamethyl-6,15-dioxa-bicyclo[10.2.1]pentadec-1(14)-en-7-one
[Molecular Formula]

C37H65NO12
[MDL Number]

MFCD09840536
[MOL File]

33396-29-1.mol
[Molecular Weight]

715.916
Chemical PropertiesBack Directory
[Appearance]

White Solid
[Melting point ]

133-1350C
[Boiling point ]

791.6±60.0 °C(Predicted)
[density ]

1.20±0.1 g/cm3(Predicted)
[storage temp. ]

-20°C Freezer
[solubility ]

Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

13.45±0.70(Predicted)
[color ]

White to Pale Yellow
[CAS DataBase Reference]

33396-29-1
Hazard InformationBack Directory
[Chemical Properties]

White Solid
[Uses]

Erythromycin A enol ether is a degradation product of erythromycin formed under acidic conditions by C6–OH internal attack on the C9 ketone to produce a cyclic enol ether. The rearrangement results in a loss of antibiotic activity. This single reaction was the prime driver for the development of second and third generation erythromycins. Erythromycin A enol ether is an important standard for stability studies.
[Uses]

Impurity E
[Definition]

ChEBI: Erythromycin a enol ether is an aminoglycoside.
[Biological Activity]

erythromycin a enol ether, also known as 8,9-anhydroerythromycin a 6,9 hemiketal, is a kind of catabolite of erythromycin a without its antibiotic properties.erythromycin a enol ether functions as a β-turn mimic of the peptide hormone motilin which leads to duodenal contractions. erythromycin a enol ether is also the agent of gastrointestinal (gi) distress [1].motilin is a kind of polypeptide hormone with 22-amino acid belonging to the motilin family. motilin could increase the migrating myoelectric complex of gastrointestinal motility, and stimulate the pepsin production. motilin could also improve peristalsis in the small intestine and empty the gut for the next meal. besides, motilin could facilitate the release of somatostatin and pancreatic polypeptide.
[storage]

Store at -20°C
[References]

[1] steinmetz w e, shapiro b l, roberts j j, et al. the structure of erythromycin enol ether as a model for its activity as a motilide.[j]. journal of medicinal chemistry, 2002, 45(22): 4899-4902.
Safety DataBack Directory
[WGK Germany ]

3
Spectrum DetailBack Directory
[Spectrum Detail]

Erythromycin A Enol Ether(33396-29-1)1HNMR
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