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ChemicalBook--->CAS DataBase List--->307926-51-8

307926-51-8

307926-51-8 Structure

307926-51-8 Structure
IdentificationBack Directory
[Name]

(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
[CAS]

307926-51-8
[Synonyms]

(S,S)Salen AI
(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&
(S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-
(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride
(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride
(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%
[Molecular Formula]

C36H52AlClN2O2
[MDL Number]

MFCD02684548
[MOL File]

307926-51-8.mol
[Molecular Weight]

607.254
Chemical PropertiesBack Directory
[Melting point ]

>350 °C(lit.)
[form ]

Powder
[color ]

yellow
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302+H312+H332
[Precautionary statements ]

P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22
[Safety Statements ]

26-36
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
Catalyst used for the asymmetric hydrocyanation of nitroolefins.
Catalyst used in the reaction of epoxides with heterocumulenes. Reactions of 307926-51-8_1
Reactions of 307926-51-8_2
Hazard InformationBack Directory
[Uses]

(S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:
  • In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
  • In the cyanation of α,β-unsaturated imides to yield saturated imides.

Spectrum DetailBack Directory
[Spectrum Detail]

(S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&(307926-51-8)IR
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