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ChemicalBook--->CAS DataBase List--->27137-85-5

27137-85-5

27137-85-5 Structure

27137-85-5 Structure
IdentificationBack Directory
[Name]

(DICHLOROPHENYL)TRICHLOROSILANE
[CAS]

27137-85-5
[Synonyms]

Isomericmixture
(dichlorophenyl)trichloro-silan
trichloro(dichlorophenyl)-silan
Trichloro(dichlorophenyl)silane
(DICHLOROPHENYL)TRICHLOROSILANE
(2,3-Dichlorophenyl)trichlorosilane
DICHLOROPHENYLTRICHLOROSILANE , MIXED ISOMERS
(DICHLOROPHENYL)TRICHLOROSILANE (ISOMERIC MIXTURE)
(DICHLOROPHENYL)TRICHLOROSILANE (MIXTURE OF ISOMERS)
Dichlorophenyltrichlorosilane, 95% (isomeric mixture)
Dichlorophenyl trichlorosilane (a little hydrochloride)
[EINECS(EC#)]

248-254-3
[Molecular Formula]

C6H3Cl5Si
[MDL Number]

MFCD00018078
[MOL File]

27137-85-5.mol
[Molecular Weight]

280.44
Chemical PropertiesBack Directory
[Appearance]

Dichlorophenyl trichlorosilane is a strawcolored liquid.
[Boiling point ]

260 °C
[density ]

1.553
[refractive index ]

1.5640
[Fp ]

150°C
[Specific Gravity]

1.553
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[EPA Substance Registry System]

Trichloro(dichlorophenyl)silane (27137-85-5)
Safety DataBack Directory
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39
[RIDADR ]

2987
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[Safety Profile]

Poison by ingestion, inhalation, subcutaneous, and intraperitoneal routes. Corrosive to the eyes, skin, and mucous membranes. On contact with moisture it releases corrosive HCl. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl-. See also CHLOROSILANES.
[Hazardous Substances Data]

27137-85-5(Hazardous Substances Data)
[Toxicity]

mammal (species unspecified),LC50,inhalation,40mg/m3 (40mg/m3),LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMABLOOD: OTHER CHANGESLIVER: FATTY LIVER DEGERATION,Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 3, Pg. 81, 1961.
Hazard InformationBack Directory
[General Description]

(DICHLOROPHENYL)TRICHLOROSILANE is a straw colored liquid with a pungent odor. Material will burn though (DICHLOROPHENYL)TRICHLOROSILANE may require some effort to ignite. (DICHLOROPHENYL)TRICHLOROSILANE is decomposed by moisture or water to hydrochloric acid with evolution of heat. (DICHLOROPHENYL)TRICHLOROSILANE is corrosive to metals and tissue. (DICHLOROPHENYL)TRICHLOROSILANE is used as an intermediate for silicones.
[Reactivity Profile]

Chlorosilanes, such as (DICHLOROPHENYL)TRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.
[Health Hazard]

Contact causes burns to skin and eyes. If inhaled, it may be harmful. Fire may produce irritating or poisonous gases. The compound is highly toxic by inhalation and is a strong irritant to the skin and eyes.
[Fire Hazard]

(DICHLOROPHENYL)TRICHLOROSILANE may burn but does not ignite readily. Flammable/poisonous gases may accumulate in tanks and hopper cars. (DICHLOROPHENYL)TRICHLOROSILANE may ignite combustibles (wood, paper, oil, etc.). The compound is a slight fire hazard when exposed to heat or flame. (DICHLOROPHENYL)TRICHLOROSILANE is decomposed by moisture or water to hydrochloric acid with the evolution of heat.
[Potential Exposure]

This material is used in silicone polymer manufacture.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water or milk. Do not induce vomiting. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy
[Shipping]

UN2987 Chlorosilanes, corrosive, n.o.s, Hazard class: 8; Labels: 8-Corrosive material.
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Chlorosilanes react vigorously with bases and both organic and inorganic acids generating toxic and/or flammable gases. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous hydrogen. Contact with ammonia may form a self-igniting material. Attacks some metals in the presence of moisture
[Description]

Dichlorophenyl trichloro-silane is a strawcolored liquid. Molecular weight=280.43; Boilingpoint=258.6℃; Vapor pressure=,1 mmHg at 18℃;Flash point=141℃. Hazard Identification (based onNFPA-704 M Rating System): Health 3, Flammability 1,Reactivity 2. Decomposes in water.
[Chemical Properties]

Dichlorophenyl trichlorosilane is a strawcolored liquid.
[storage]

(1) Color Code—White: Corrosive or ContactHazard; Store separately in a corrosion-resistant location.(2) Color Code—Blue: Health Hazard/Poison: Store in asecure poison location. Prior to working with this chemicalyou should be trained on its proper handling and storage.Dichlorophenyl trichloro-silane should be stored to avoidcontact with moisture or with combustible materials, suchas wood, paper, and oil.
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