| Identification | Back Directory | [Name]
Poly(tetrahydrofuran) | [CAS]
25190-06-1 | [Synonyms]
ptmg
PTHF
b2000
ptg100
ptg200
ptg300
ptg400
ptg500
ptg500p
polymeg
teracol
ptmg1000
ptmg2000
qopolymeg
polifurit
polyfurit
teracol30
terathane
PTMEG 250
PTMEG-TG
PTMEG 1400
PTMEG 1800
PTMEG 2000
teracol650
PTMEG 1000
polymeg600
polymeg650
polyfurite
polymeg1000
polymeg1020
polymeg2000
polymeg2010
teracol1000
teracol2000
PTMEG 650 S
Poly THF 250
Poly THF 650
PTMEG 1000 S
hiprenemc532
polyfurit1000
qopolymeg1000
terathane1000
terathane2900
thfpolymer,sru
Terathane?1400
TERATHANE(R) 1400
Poly THF 1000/2000
polybutyleneglycol
poly(butyleneoxide)
POLYTETRAHYDROFURAN
POLY(1,4-BUTANEDIOL)
POLYTETRAHYDROFURAN 250
poly(oxybutylene)glycol
poly(oxytetramethylene)
polytetramethyleneglycol
POLYTETRAHYDROFURAN 1000
POLYTETRAHYDROFURAN 2000
POLYTETRAHYDROFURAN 1400
POLYTETRAHYDROFURAN 1800
POLYTETRAHYDROFURAN 650 S
poly(tetramethyleneether)
poly(tetramethyleneglycol)
glycols,polytetramethylene
POLYTETRAHYDROFURAN 1000 S
Tetrahydrofuranhomopolymer
poly(oxytetramethylene)diol
TERATHANE650POLYETHERGLYCOL
Poly(tetramethylene Oxide)
TERATHANE1000POLYETHERGLYCOL
TERATHANE1400POLYETHERGLYCOL
TERATHANE2000POLYETHERGLYCOL
TERATHANE2900POLYETHERGLYCOL
poly(oxy-1,4-butylene)glycol
POLY(1,4-OXYBUTYLENE) GLYCOL
tetrahydrofuranhomopolymersru
tetrahydrofuran-sym-polyether
poly(tetramethyleneether)diol
polytetramethyleneetherglycols
poly(tetramethyleneoxide)glycol
POLY (TETRAMETHYLENE OXIDE) 650
POLY(TETRAMETHYLENE OXIDE) 2,000
POLY (TETRAMETHYLENE OXIDE) 1,000
POLY (TETRAMETHYLENE OXIDE) 1,400
POLY(TETRAMETHYLENE ETHER) GLYCOL
TERATHANE(R) 650 POLYETHER GLYCOL
POLY(1,4-BUTYLENEGLYCOL)M.WT>1000
TERATHANE(R) 1400 POLYETHER GLYCOL
TERATHANE(R) 2000 POLYETHER GLYCOL
TERATHANE(R) 2900 POLYETHER GLYCOL
TERATHANE(TM) 650 POLYETHER GLYCOL
TERATHANE(R) 1000 POLYETHER GLYCOL
TERATHANE(TM) 2900 POLYETHER GLYCOL
TERATHANE(TM) 2000 POLYETHER GLYCOL
POLYTETRAMETHYLENE ETHER GLYCOL 250
POLYTETRAMETHYLENE ETHER GLYCOL 1400
POLYTETRAMETHYLENE ETHER GLYCOL 1800
POLYTETRAMETHYLENE ETHER GLYCOL 2000
POLYTETRAMETHYLENE ETHER GLYCOL 1000
POLYTETRAMETHYLENE ETHER GLYCOL 650 S
Poly(tetrahydrofuran) average Mn ~250
Poly(tetrahydrofuran) average Mn ~650
POLYTETRAMETHYLENE ETHER GLYCOL 1000 S
Poly(tetrahydrofuran) average Mn ~1,000
Poly(tetrahydrofuran) average Mn ~2,000
TETRAMETHYLENE ETHER GLYCOL 650 POLYMER
TETRAMETHYLENE ETHER GLYCOL 1000 POLYMER
TETRAMETHYLENE ETHER GLYCOL 2000 POLYMER
TETRAMETHYLENE ETHER GLYCOL 2900 POLYMER
POLYTETRAHYDROFURAN 1000 (STABILISED WIT
α-hydro-ω-hydroxypoly(oxy-1,4-butanediyl)
POLYLETRAHYDROFURAN, LINEAR CHAIN POLYMER
POLYTETRAHYDROFURAN, LINEAR-CHAIN POLYMER
POLYETETRAHYDROFURAN, LINEAR-CHAIN POLYMER
Poly(tetrahydrofuran)Molecular weight 2000
Poly(oxy-1,4-butanediyl),a-hydro-w-hydroxy-
alpha-hydro-omega-hydroxy-poly(oxy-4-butanediyl)
ALPHA-HYDRO-OMEGA-HYDROXYPOLY(OXY-1,4-BUTANEDIYL)
terathane 2000 polyether glycol (poly-tetrahydrof
.alpha.-Hydro-.omega.-hydroxypoly(oxytetramethylene)
4-butanediyl),.alpha.-hydro-.omega.-hydroxy-poly(oxy-1
Poly(oxy-1,4-butanediyl), .alpha.-hydro-.omega.-hydroxy-
POLYTETRAHYDROFURAN, LINEAR-CHAIN POLYME R, AVERAGE MN CA. 250
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol)
Polytetrahydrofuran1000,stabilisedwith2,6-di-tert-butyl-4-methylphenol
TERATHANE 650 POLYETHER GLYCOL (POLY-TET RAHYDROFURAN, LINEAR-CHAIN POLYMER)
TERATHANE 2900 POLYETHER GLYCOL (POLY-TE TRAHYDROFURAN, LINEAR-CHAIN POLYMER)
TERATHANE 1000 POLYETHER GLYCOL (POLY-TE TRAHYDROFURAN, LINEAR-CHAIN POLYMER)
TERATHANE 1400 POLYETHER GLYCOL (POLY-TE TRAHYDROFURAN, LINEAR-CHAIN POLYMER)
TERATHANE 2000 POLYETHER GLYCOL (POLY-TE TRAHYDROFURAN, LINEAR-CHAIN POLYMER)
Poly(tetrahydrofuran) average Mn ~2,900, contains 300-500 ppM BHT as stabilizer
Poly(tetrahydrofuran) average Mn ~2,000, contains 200-350 ppm BHT as stabilizer
PolytetramethyleneetherglycolPTMEG,stabilisedwith2,6-di-tert-butyl-4-methylphenol)
Poly(tetrahydrofuran),α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol)
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Poly(tetrahydrofuran)
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane(R)650 polyether glycol
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane(R)1000 polyether glycol
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane(R)1400 polyether glycol
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane(R)2000 polyether glycol
α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane(R)2900 polyether glycol
Poly(tetrahydrofuran),α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane650 polyether glycol
Poly(tetrahydrofuran),α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane1000 polyether glycol
Poly(tetrahydrofuran),α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane2000 polyether glycol
Poly(tetrahydrofuran),α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane2900 polyether glycol
Poly(tetrahydrofuran),α-Hydro-ω-hydroxypoly(oxy-1,4-butanediyl), Poly(1,4-butanediol), Terathane1400 polyether glycol | [EINECS(EC#)]
203-786-5 | [Molecular Formula]
C16H33O5X2 | [MDL Number]
MFCD00148879 | [MOL File]
25190-06-1.mol | [Molecular Weight]
305.43 |
| Hazard Information | Back Directory | [Chemical Properties]
mp 11-38 °C 100-4,400 mPa.s @ 40 °C | [Definition]
ChEBI: A macromolecule composed of repeating oxybutylene units. | [Preparation]
Low molecular weight polymers of tetrahydrofuran were introduced commercially in 1955. The polymers were intended for use in the preparation of
flexible polyurethane foams, being terminated by hydroxyl groups:
Although these polyethers produced good foams they were rather expensive
and were soon displaced by the cheaper propylene oxide-based polyethers.
However, these polymers of tetrahydrofuran (commonly called poly(oxytetramethylene)glycol) now find use in the preparation of polyamide, polyester and polyurethane thermoplastic elastomers.
Details of the manufacture of polytetrahydrofuran have not been disclosed.
Polymerization of tetrahydrofuran can be effected only by cationic initiators.
Combinations of metal halides with water are not effective but protic acids
(e.g. HCl04) and oxonium salts (e.g. (C2H5￡?3O+BF4-) are efficient initiators.
Polymerization occurs by a ring-opening mechanism involving a tertiary
oxonium ion, e.g.
| [Solubility in organics]
Alcohol, slightly in water; Insoluble in ether |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
1
| [RTECS ]
MD0916000
| [TSCA ]
TSCA listed | [HS Code ]
3907 20 20 | [Toxicity]
LD50 orally in Rabbit: > 5000 mg/kg |
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