| Identification | Back Directory | [Name]
POLY(VINYL ETHYL ETHER) | [CAS]
25104-37-4 | [Synonyms]
ebdc
edbc
ehbc
ehb-m
lutonala25
lutonala50
luthonala20
bakeliteehbc
bakeliteehbm
ethoxy-ethenpolymers
ethylvinyletherpolymer
vinylethyletherpolymer
Poly(vinyl ethyleether)
ethoxy-ethenhomopolymer
POLY(VINYL ETHYL ETHER)
POLY(ETHYL VINYL ETHER)
VINYL ETHYL ETHER RESIN
ether,ethylvinyl,polymers
ethylvinyletherhomopolymer
Ethene,ethoxy-,homopolymer
vinylethyletherhomopolymer
VinylethylethereesinHighMWt
Vinyl Ethyl Ether Resin (Low M.Wt.)
Poly(vinyl ethyl ether), low molecular weight
Poly(ethyl vinyl ether) average Mw ~3,800 by GPC
5-ethyl-5-(6-oxo-1-cyclohexen-1-yl)-barbituric acid
5-(3or6-oxo-1-cyclohexen-1-yl)-5-ethylbarbituricacid
5-ethyl-5-(3or6-oxo-1-cyclohexen-1-yl)-barbituricaci
5-ethyl-5-(3or6-oxo-1-cyclohexen-1-yl)barbituricacid | [EINECS(EC#)]
204-085-7 | [Molecular Formula]
C4H8N2S4 | [MDL Number]
MFCD00084462 | [MOL File]
25104-37-4.mol | [Molecular Weight]
212.38 |
| Chemical Properties | Back Directory | [Appearance]
opaque amber viscous liquid | [density ]
0.968 g/mL at 25 °C(lit.)
| [Tg]
-60 | [vapor pressure ]
22.5 mm Hg ( 20 °C)
| [refractive index ]
n20/D 1.454(lit.)
| [Fp ]
140 | [form ]
Viscous liquid | [InChI]
InChI=1S/C4H8O/c1-3-5-4-2/h3H,1,4H2,2H3 | [InChIKey]
FJKIXWOMBXYWOQ-UHFFFAOYSA-N | [SMILES]
O(C=C)CC | [CAS DataBase Reference]
25104-37-4 | [EPA Substance Registry System]
Poly(vinyl ethyl ether) (25104-37-4) |
| Hazard Information | Back Directory | [Chemical Properties]
opaque amber viscous liquid | [Hazard]
Moderately toxic. | [Uses]
Poly(ethyl vinyl ether) can used as a plasticiser for cellulose nitrate and cellulose resin lacquers, as a base for pressure-sensitive adhesives in films and tapes, especially in surgical applications. Also used for non-irritating surgical casts requiring moisture permeability and to impart dry-film flexibility and increased viscosity of photochemical resist-coating compositions. | [Preparation]
To a flask containing 200 gm of benzene is added 1.0 gm of aluminum chloride. The mixture is stirred vigorously to suspend the catalyst and then the gradual addition of 200 gm (2.78 moles) of vinyl ether is begun. The reaction is exothermic, and when the temperature rises to 60°-80°C the addition is slowed so that only 1-2 gm of vinyl ethyl ether is added at one time. Polymerization is detected by the onset of turbidity and a slight brown color. When the brown color disappears, the next increment of vinyl ethyl ether is added. After the complete addition the reaction mixture is heated to 80°C. The benzene and volatiles are steam-distilled off, and the residue amounts to about 144 gm (72%) of a yellow balsamlike product.
Preparation of Poly(vinyl ethyl ether) Using Aluminum Chloride Catalyst | [Safety Profile]
Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors. | [Solubility in organics]
alcohols, aliphatic, aromatic and chlorinated hydrocarbons, esters, ketones |
| Safety Data | Back Directory | [Safety Statements ]
24/25 | [WGK Germany ]
3
| [RTECS ]
CQ6693000
| [Autoignition Temperature]
446 °F | [TSCA ]
TSCA listed | [Toxicity]
LD50 intraperitoneal in mouse: 2590mg/kg |
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