| Identification | Back Directory | [Name]
TERT-BUTYL 4-(BROMOMETHYL)PHENYLCARBAMATE | [CAS]
239074-27-2 | [Synonyms]
tert-Butyl (4-(bromomethyl)
N-Boc-4-(broMoMethyl)aniline
TERT-BUTYL 4-(BROMOMETHYL)PHENYLCARBAMATE
tert-butyl N-[4-(bromomethyl)phenyl]carbamate
4-(1,1-dimethylethoxycarbonylamino)benzylbromide
Carbamic acid, [4-(bromomethyl)phenyl]-, 1,1-dimethylethyl e...
Carbamic acid, [4-(bromomethyl)phenyl]-, 1,1-dimethylethyl ester
Carbamic acid, N-[4-(bromomethyl)phenyl]-, 1,1-dimethylethyl ester | [Molecular Formula]
C12H16BrNO2 | [MDL Number]
MFCD11616718 | [MOL File]
239074-27-2.mol | [Molecular Weight]
286.16 |
| Chemical Properties | Back Directory | [Boiling point ]
309.7±25.0 °C(Predicted) | [density ]
1.376±0.06 g/cm3(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [pka]
13.49±0.70(Predicted) |
| Hazard Information | Back Directory | [Synthesis]
To a 1 L round bottom flask was added (4-hydroxymethyl-phenyl)-carbamic acid tert-butyl ester (22.3 g, 0.10 mol) obtained from Examples 2pp through 2ooo, Step 1, dichloromethane (400 mL) and triphenylphospine (31.5 g, 0.12 mol). Upon cooling to 0 °C, N-bromosuccinimide (19.6 g, 0.11 mmol) was added in small portions, and the reaction was allowed to warm to room temperature and stirred under nitrogen for 1 h. The mixture was transferred into a large flask, and hexanes were added until the solution became turbid. The solution was eluted through a plug of silica (300 g) with 1:9 ethyl acetate: hexanes and concentrated to yield Tert-Butyl 4-(bromomethyl)phenylcarbamate (12.8 g, 0.057 mol, 57 percent) as a white solid.
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| Company Name: |
Energy Chemical
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021-021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
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