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ChemicalBook--->CAS DataBase List--->218290-24-5

218290-24-5

218290-24-5 Structure

218290-24-5 Structure
IdentificationBack Directory
[Name]

(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
[CAS]

218290-24-5
[Synonyms]

(R,R)-DACH-pyridyl Trost ligand
(R,R)-DACH-pyridyl Trost ligand 95%
Diaminocyclohexanediylbispyridinecarboxamide
2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine
trans-1,2-Bis(2-pyridinecarboxamido)cyclohexane
(1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane
1R,2R- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide)
(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%
(1R,2R)-N,N'-1,2-Diaminocyclohexanediylbis(2-pyridinec arboxamide),99%e.e.
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%
(-)-N,N''-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (R,R)-DACH-Pyridyl Trost Ligand
[Molecular Formula]

C18H20N4O2
[MDL Number]

MFCD02684543
[MOL File]

218290-24-5.mol
[Molecular Weight]

324.38
Chemical PropertiesBack Directory
[Melting point ]

170°C
[alpha ]

-95° (c 1, CH3OH)
[form ]

Powder
[color ]

off-white
Safety DataBack Directory
[Risk Statements ]

36/37/38-22
[Safety Statements ]

26-36/37/39-36/37
Questions And AnswerBack Directory
[Reaction]

  1. Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
  2. Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers.
Reactions of 218290-24-5
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