Identification | Back Directory | [Name]
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide | [CAS]
200132-54-3 | [Synonyms]
A16450 O-ALLYL-N-(9-ANTHRACENYLMETHYL)CINCHONIDINIUM BROMIDE O-Allyl-N-[(9-anthracenyl)methyl]cinchonidium bromide O-Allyl-1-(anthracen-9-ylmethyl)cinchonidinium bromide O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide 90% (-)-O-(9)-Allyl-N-(9-anthracenylmethyl) cinchonidiniumbromide (-)-O-(9)-ALLYL-N-(9-ANTHRACENYLMETHYL) CINCHONIDINIUM BROMIDE Cinchonanium, 1-(9-anthracenylmethyl)-9-(2-propenyloxy)-, bromide, (8α,9R)- 4-((1R)-((1-(Anthracen-9-yl)but-3-en-2-yl)oxy)((2S)-5-vinylquinuclidin-2-yl)methyl)quinolin-1-ium bromide 4-[[1-(anthracen-9-ylmethyl)-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-prop-2-enoxymethyl]quinoline,bromide (1S,2S,4S,5R)-2-((R)-(allyloxy)(quinolin-4-yl)methyl)-1-(anthracen-9-ylmethyl)-5-vinylquinuclidin-1-ium bromide 4-[(R)-[(2S,4S,5R)-1-(anthracen-9-ylmethyl)-5-ethenyl-1-azoniabicyclo[2.2.2]octan-2-yl]-prop-2-enoxymethyl]quinoline | [Molecular Formula]
C37H37BrN2O | [MDL Number]
MFCD01632446 | [MOL File]
200132-54-3.mol | [Molecular Weight]
605.61 |
Chemical Properties | Back Directory | [Melting point ]
170 °C (dec.)(lit.) | [alpha ]
-340 º (C=0.45 IN CHLOROFORM) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [optical activity]
[α]20/D 345±30°, c = 0.45 in chloroform |
Hazard Information | Back Directory | [Uses]
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide can catalyze the asymmetric alkylation of tert-butyl glycinate-benzophenone Schiff base with different arylmethyl bromides in a micellar medium. | [General Description]
O-Allyl-N-(9-anthracenylmethyl)cinchonidinium bromide is a cinchona-based chiral phase-transfer catalyst (PTC) that can be used in asymmetric synthesis. It can be prepared from N-(9-anthracenylmethyl)cinchonindinium chloride. |
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Energy Chemical
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