| Identification | Back Directory | [Name]
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) | [CAS]
192139-90-5 | [Synonyms]
-N-(p-Toluenesulfonyl)
RuCl[(S,S)- Tsdpen](p-cyMene)
RuCl(p-cymene)[(S,S)-Ts-DPEN]
-1,2-diphenylethanediamine(chloro)
[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)]
RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
[(η-6-CyMene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaMinato]rutheniuM] chloride]
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II)
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%
Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(S,S)-Tsdpen](p-cyMene)
Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(S,S)-Tsdpen](p-cyMene)
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
[N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium
[N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-methylethyl)benzene]-ruthenium | [Molecular Formula]
C31H35ClN2O2RuS | [MDL Number]
MFCD09953484 | [MOL File]
192139-90-5.mol | [Molecular Weight]
631.17 |
| Chemical Properties | Back Directory | [Melting point ]
>175 °C | [alpha ]
178o (C=0.5 IN CHLOROFORM) | [storage temp. ]
2-8°C | [solubility ]
soluble in Chloroform, DCM, Ethyl Acetate | [form ]
solid | [color ]
yellow to dark brown | [optical activity]
[α]20/D +178°, c = 0.5 in chloroform | [Sensitive ]
air sensitive | [InChIKey]
DCJKLKCGNMDXFR-MNPNNRAMNA-M | [SMILES]
[Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r| |
| Hazard Information | Back Directory | [Chemical Properties]
Solid | [Uses]
Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut | [General Description]
RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines. |
| Questions And Answer | Back Directory | [Reaction]
This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
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