| Identification | Back Directory | [Name]
Tributyltin azide | [CAS]
17846-68-3 | [Synonyms]
SKL1111
Nsc179738
AzidotributyL
AZIDOTRIBUTYLTIN
TRIBUTYLTIN AZIDE
TRI-N-BUTYLAZIDOTIN
azidotributyltin(iv)
Azidotributylstannane
TriDing Jidietin nitride
Tributylstannanylium Azide
Azidotri-n-butyltin(IV), 98%
Tributyltin azide ISO 9001：2015 REACH | [Molecular Formula]
C12H27N3Sn | [MDL Number]
MFCD00216557 | [MOL File]
17846-68-3.mol | [Molecular Weight]
332.07 |
| Chemical Properties | Back Directory | [Boiling point ]
120°C/0.2mmHg | [density ]
1.212 g/mL at 25 °C(lit.)
| [refractive index ]
1.5745 | [Fp ]
>230 °F
| [solubility ]
Miscible with toluene, hexane, acetonitrile and tetrahydrofuran. | [Specific Gravity]
1.212 | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [InChI]
InChI=1S/3C4H9.N3.Sn/c3*1-3-4-2;1-3-2;/h3*1,3-4H2,2H3;;/q;;;-1;+1 | [InChIKey]
JKVRTUCVPZTEQZ-UHFFFAOYSA-N | [SMILES]
[Sn](N=[N+]=[N-])(CCCC)(CCCC)CCCC |
| Hazard Information | Back Directory | [Description]
Tributyltin azide is a heterocyclic organic compound that is used in organic synthesis. It has shown antihypertensive activity and the ability to inhibit fatty acid synthesis. Tributyltin azide has also been shown to have biological properties, such as the coordination of proteins and enzymes.
| [Uses]
Tributylstannanylium Azide is used in preparation method of Polycaprolactone-based Polyamide composite material. | [Synthesis]
A cooled solution of sodium azide (4.10 g, 63.0 mmol) in water (13 mt) at 8°C BusSnCI (17 1 ml) is added dropwise while stirring the solution. After 2h of stirring at 8°C, dichloromethane (38 mi) is added, stirred for another 5 minutes, and phases separated. The water phase is washed with dichloromethane (13 ml). Combined organic phases are washed with 10% NaCI (13 ml) and distilled water (13 ml). The organic phase is dried with sodium sulfate (6.34 g), and the solvent is removed under reduced pressure to give the oily product Tributyltin azide (19.2 g, 91.8%).
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