Identification | Back Directory | [Name]
FEMA 3766 | [CAS]
17587-33-6 | [Synonyms]
FEMA 3766 2,6-Nonadienal T2 T6 NONADIENAL (e,e)-6-nonadienal (2E,6E)-2,6-Nonadienal 2,6-Nonadienal, (E,E)- (2E,6E)-nona-2,6-dienal 2,6-Nonadienal, (2E,6E)- 2,6-trans,trans-Nonadienal 2-trans-6-trans-Nonadienal (2E,6E)-nona-2,6-dien-1-al TRANS 2 TRANS 6-NONADIENAL TRANS, TRANS-2,6-NONADIENAL TRANS-2,TRANS-6-NONADIEN-1-AL trans-2,trans-6-Nonadienal,95% TRANS TRANS-2 6-NONADIENAL 93+% | [EINECS(EC#)]
241-557-1 | [Molecular Formula]
C9H14O | [MOL File]
17587-33-6.mol | [Molecular Weight]
138.21 |
Chemical Properties | Back Directory | [Appearance]
clear colorless to pale yellowish liquid | [Boiling point ]
57 °C0.6 mm Hg(lit.)
| [density ]
0.875 g/mL at 25 °C(lit.)
| [FEMA ]
3766 | 2-TRANS-6-TRANS-NONADIENAL | [refractive index ]
n20/D 1.471(lit.)
| [Fp ]
189 °F
| [storage temp. ]
0-6°C | [solubility ]
Practically insoluble in water, soluble in alcohol, Propylene glycol and oils. | [form ]
Almost colourless or very pale yellowish oil. | [Odor]
at 1.00 % in dipropylene glycol. fresh citrus green cucumber melon | [Odor Type]
green | [JECFA Number]
1187 | [LogP]
2.60 | [EPA Substance Registry System]
2,6-Nonadienal, (2E,6E)- (17587-33-6) |
Hazard Information | Back Directory | [Chemical Properties]
clear colorless to pale yellowish liquid | [Description]
2-trans-6-trans.Nonadienahas a tallowy odor. | [Occurrence]
Reported found in soybean oil, beef tallow, cold-stored butter, mango, lingonberry, cucumber, corn mint oil,
lean fish, beer, trassi, buckwheat, shrimp and rooibus tea (Aspalathus linearis). | [Uses]
(2E,6E)-2,6-Nonadienal is a useful building block for organic synthesis. | [Application]
2-trans, 6-trans-Nonadienal would particularly be used in imitation Cucumber and as a trace ingredient in many green and fruity flavour types.
| [Production Methods]
Most methods start with 3-Hexenol. 1) via Hexenyl iodide and its Grignard compound, with Acrolein to the carbinol. By treatment with Phosphorous tribromide and saponification is obtained the alcohol Nonadienol which can be oxidized to 2-trans, 6-trans-Nonadienal by Chromic acid oxidation. 2) from Dipropargyl via Octadi-yne to Nonadiynal-diethylacetal, followed by selective hydrogenation to Nonadienal diethylacetal which yields 2-trans, 6-trans-Nonadienal by acid hydrolysis.
| [Aroma threshold values]
Detection: 0.09 ppb | [Taste threshold values]
Taste characteristics at 1 ppm: fresh, green cucumber skin and watermelon with a fatty nuance |
|
Company Name: |
Energy Chemical
|
Tel: |
021-021-58432009 400-005-6266 |
Website: |
http://www.energy-chemical.com |
Company Name: |
Sigma-Aldrich
|
Tel: |
021-61415566 800-8193336 |
Website: |
https://www.sigmaaldrich.cn |
Company Name: |
BOC Sciences
|
Tel: |
|
Website: |
https://www.bocsci.com |
Company Name: |
Pyrazine Specialties, Inc.
|
Tel: |
(404) 524-6744 |
Website: |
www.approvedhomemanagement.com/ShowSupplierProductsList170/0_EN.htm |
|