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ChemicalBook--->CAS DataBase List--->171860-68-7

171860-68-7

171860-68-7 Structure

171860-68-7 Structure
IdentificationBack Directory
[Name]

CYCLOPENTYLZINC BROMIDE
[CAS]

171860-68-7
[Synonyms]

CYCLOPENTYLZINC BROMIDE
Zinc, bromocyclopentyl-
bromozinc(1+),cyclopentane
cyclopentylzinc(II) broMide
cyclopentylzinc bromide solution
Cyclopentylzinc bromide, 0.50 M in THF
Cyclopentylzinc bromide solution 0.5 in THF
Cyclopentylzinc broMide solution 0.5 M in THF
Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal
CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN
Cyclopentylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
Cyclopentylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
[Molecular Formula]

C5H9BrZn
[MDL Number]

MFCD00671991
[MOL File]

171860-68-7.mol
[Molecular Weight]

214.42
Chemical PropertiesBack Directory
[density ]

0.955 g/mL at 25 °C
[Fp ]

1 °F
[storage temp. ]

2-8°C
[Water Solubility ]

Reacts with water.
[Sensitive ]

Air Sensitive
[Exposure limits]

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Safety DataBack Directory
[Symbol(GHS) ]


GHS02,GHS07,GHS08,GHS05
[Signal word ]

Danger
[Hazard statements ]

H225-H261-H302-H315-H319-H335-H351-H314-H318-H333
[Precautionary statements ]

P223-P303+P361+P353-P305+P351+P338-P405-P501a-P210-P231+P232-P280-P370+P378-P402+P404-P403+P235
[Hazard Codes ]

F,Xn
[Risk Statements ]

11-14-19-22-36/37/38-40-36/37
[Safety Statements ]

16-26-33-36-36/37
[RIDADR ]

UN 3399 4.3/PG 2
[WGK Germany ]

1
[HazardClass ]

4.3
[HS Code ]

29319090
Hazard InformationBack Directory
[Uses]

Cyclopentylzinc bromide is an organozinc reagent that can be used in:
  • The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
  • Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
  • The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

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