Identification | Back Directory | [Name]
CYCLOPENTYLZINC BROMIDE | [CAS]
171860-68-7 | [Synonyms]
CYCLOPENTYLZINC BROMIDE Zinc, bromocyclopentyl- bromozinc(1+),cyclopentane cyclopentylzinc(II) broMide cyclopentylzinc bromide solution Cyclopentylzinc bromide, 0.50 M in THF Cyclopentylzinc bromide solution 0.5 in THF Cyclopentylzinc broMide solution 0.5 M in THF Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN Cyclopentylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade Cyclopentylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles | [Molecular Formula]
C5H9BrZn | [MDL Number]
MFCD00671991 | [MOL File]
171860-68-7.mol | [Molecular Weight]
214.42 |
Chemical Properties | Back Directory | [density ]
0.955 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
2-8°C | [Water Solubility ]
Reacts with water. | [Sensitive ]
Air Sensitive | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin) OSHA: TWA 200 ppm(590 mg/m3) NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
Hazard Information | Back Directory | [Uses]
Cyclopentylzinc bromide is an organozinc reagent that can be used in:
- The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
- Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
- The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.
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Alfa Aesar
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Sigma-Aldrich
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