Identification | Back Directory | [Name]
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) | [CAS]
169689-05-8 | [Synonyms]
Rostligand (S,S)-DACH-phenyl ligand (1S,2S)-(-)-1,2-TROST LIGAND 1S,2S- DHAC-Phenyl Trost Ligand (S,S)-DACH-phenyl Trost ligand 95% (S,S)-DACH-Phenyl Trost Ligand (S,S)-DACH-phenyl Trost ligand 95% (1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e. 1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl) BenzaMide,N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphi
no)benzamide] (1S,2S)-(-)-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl) (1S,2S)-(¨C)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N''-BIS(2''-DIPHENYLPHOSPHINOBENZOYL) TROST LIGAND (S,S)-DACH-phenyl Trost ligand,(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(S,S)-DACH-PhenylTrostLigand (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand | [Molecular Formula]
C44H40N2O2P2 | [MDL Number]
MFCD01631274 | [MOL File]
169689-05-8.mol | [Molecular Weight]
690.75 |
Chemical Properties | Back Directory | [Melting point ]
134-136°C | [alpha ]
-134o (C=1 IN METHANOL) | [Boiling point ]
817.0±65.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Powder | [pka]
13.35±0.40(Predicted) | [color ]
white to off-white | [optical activity]
[α]20/D -134°, c = 1 in methanol |
Questions And Answer | Back Directory | [Reaction]
The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.
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