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ChemicalBook--->CAS DataBase List--->158923-09-2

158923-09-2

158923-09-2 Structure

158923-09-2 Structure
IdentificationBack Directory
[Name]

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
[CAS]

158923-09-2
[Synonyms]

JOSIPHOS SL-J004-1
OSIPHOS SL-J004-1
(R)1[(1S)2(di-C-hex
(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET
(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine >=97%
(S)-(-)-l-[(S)-2-( Dicyclohexylphosphino)ferroceny1] ethyldicyclohexylphosphino
(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97%
(r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas)
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97%
Josiphos SL-J004-1, (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS)
[Molecular Formula]

C36H44FeP2 10*
[MDL Number]

MFCD00800280
[MOL File]

158923-09-2.mol
[Molecular Weight]

594.53
Chemical PropertiesBack Directory
[alpha ]

-100° ±5° (c 0.5, CHCl3)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

orange
Hazard InformationBack Directory
[Chemical Properties]

Red crystal
[Uses]

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:
  • To prepare iridium metal complex (IrIJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
  • In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

[General Description]

sold in collaboration with Solvias AG
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[F ]

10
[HS Code ]

29319090
Questions and Answers (Q&A)Back Directory
[Reactions]

1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .
Reactions of 158923-09-2
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