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ChemicalBook--->CAS DataBase List--->1450-75-5

1450-75-5

1450-75-5 Structure

1450-75-5 Structure
IdentificationBack Directory
[Name]

5-Bromo-2-hydroxyacetophenone
[CAS]

1450-75-5
[Synonyms]

-Bromo-2’
AKOS BBS-00006622
5-BroMo-2-hydroxyace
2-ACETYL-4-BROMOPHENOL
5-Methyl-6-Hydroxysalicylate
5-BROMO-2-HYDROXYACETOPHENONE
5'-BROMO-2'-HYDROXYACETOPHENONE
2’-hydroxy-5’-bromoacetophenone
5’-bromo-2’-hydroxy-acetophenon
1-(5-bromo-2-hydroxyphenyl)-ethanon
1-(5-BROMO-2-HYDROXYPHENYL)ETHANONE
5'-Bromo-2'-hydroxyacetophenone,98%
5'-BroMo-2'-hydroxyacetophenone, 97+%
1-(3-broMophenyl)-2-hydroxyethan-1-one
17459
5''-BROMO-2''- HYDROXYACETOPHENONE
5'-bromo-2'-hydroxyacetophenone ,1-(5-bromo-2-hydroxy)ethanone
1-(5-Bromo-2-hydroxyphenyl)ethan-1-one, 2-Acetyl-4-bromophenol
5-Bromo-2-Hydroxy Acetophenone 5'-Bromo-2'-Hydroxy Acetophenone
5'-BroMo-2'-hydroxyacetophenone (2'-hydroxy-5'-broMoacetophenone)
[EINECS(EC#)]

604-457-2
[Molecular Formula]

C8H7BrO2
[MDL Number]

MFCD00191850
[MOL File]

1450-75-5.mol
[Molecular Weight]

215.04
Chemical PropertiesBack Directory
[Appearance]

White to pale yellow crystalline powder
[Melting point ]

58-61 °C(lit.)
[Boiling point ]

135-143 °C(Press: 16 Torr)
[density ]

1.586±0.06 g/cm3(Predicted)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Soluble in Chloroform
[form ]

Solid
[pka]

9.59±0.18(Predicted)
[color ]

White to pale yellow
[LogP]

3.110 (est)
Hazard InformationBack Directory
[Chemical Properties]

White to pale yellow crystalline powder
[Uses]

5?-Bromo-2?-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2?-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N?-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.
[Preparation]

Preparation by Fries rearrangement of 4-bromophenyl acetate with aluminium chloride without solvent between 110° and 160° (84–91%).
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[RTECS ]

KM5556350
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29147000
[Toxicity]

mouse,LD50,intraperitoneal,> 1gm/kg (1000mg/kg),Indian Journal of Chemistry, Section B: Organic Chemistry, Including Medicinal Chemistry. Vol. 20, Pg. 480, 1981.
Spectrum DetailBack Directory
[Spectrum Detail]

5-Bromo-2-hydroxyacetophenone(1450-75-5)MS
5-Bromo-2-hydroxyacetophenone(1450-75-5)IR1
5-Bromo-2-hydroxyacetophenone(1450-75-5)IR2
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