| Identification | Back Directory | [Name]
METHOXYMETHYL PHENYL SULFIDE | [CAS]
13865-50-4 | [Synonyms]
ALPHA-METHOXYTHIOANISOLE
Methoxy(phenylthio)methane
Phenylthiomethylmethyl ether
methoxymethylsulfanylbenzene
[(METHOXYMETHYL)THIO]BENZENE
METHOXYMETHYL PHENYL SULFIDE
METHYL PHENYLTHIOMETHYL ETHER
MethoxymethylPhenylSulfide>
(MethoxyMethyl)(phenyl)sulfane
Benzene, [(methoxymethyl)thio]-
alpha-Methoxythioanisole
Methyl Phenylthiomethyl Ether | [Molecular Formula]
C8H10OS | [MDL Number]
MFCD00008496 | [MOL File]
13865-50-4.mol | [Molecular Weight]
154.23 |
| Chemical Properties | Back Directory | [Boiling point ]
113-114 °C18 mm Hg(lit.)
| [density ]
1.047 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.5632(lit.)
| [Fp ]
203 °F
| [form ]
clear liquid | [color ]
Colorless to Almost colorless |
| Hazard Information | Back Directory | [Uses]
Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide. | [Preparation]
Methoxymethyl phenyl sulfide can be prepared by condensing thiophenol with chloromethyl methyl ether under base catalysis or by condensing thiophenol with dimethoxymethane under boron trifluoride ether catalysis. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 51, p. 879, 1986 DOI: 10.1021/jo00356a025 | [General Description]
Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone. |
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