| Identification | Back Directory | [Name]
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) | [CAS]
138517-61-0 | [Synonyms]
TROST LIGAND
(1R,2R)-(+)-1,2-TROST LIGAND
1R,2R- DHAC-Phenyl Trost Ligand
(R,R)-DACH-phenyl Trost ligand
(R,R)-DACH-phenyl Trost ligand 95%
N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi
no)benzamide]
Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
(1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl
(1R,2R)-N,N'-(Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide)
(1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-di-phenylphoshinobenzoyl)
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi
no)benzamide],99%e.e.
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 98% (R,R)-DACH-Phenyl
(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(R,R)-DACH-PhenylTrostLigand | [Molecular Formula]
C44H40N2O2P2 | [MDL Number]
MFCD01631273 | [MOL File]
138517-61-0.mol | [Molecular Weight]
690.75 |
| Chemical Properties | Back Directory | [Melting point ]
134-136°C | [alpha ]
+130° (c 1.0, methanol) | [Boiling point ]
817.0±65.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Powder | [pka]
13.35±0.40(Predicted) | [color ]
white to off-white | [optical activity]
[α]20/D +131°, c = 1 in methanol |
| Questions And Answer | Back Directory | [Reaction]
The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.
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