Identification | Back Directory | [Name]
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) | [CAS]
131864-67-0 | [Synonyms]
2,6-bis((4R)-(+)-isopropyl-2-oxazolin-2-yl)pyridi (R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2,6-BIS[(4R)-(+)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE (+)-2,6-BIS[(4R)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE 2,6-bis((R)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine 2,6-Bis[(4R)-(+)-isopropyl-2-oxazolin-2-yl]pyridine 99% 2,6-Bis[(4R)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e. (R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE) (+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,97% (+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine,98+% (+)-2,6-Bis[(4R)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (R)-(i-Pr)-pybox | [Molecular Formula]
C17H23N3O2 | [MDL Number]
MFCD01321334 | [MOL File]
131864-67-0.mol | [Molecular Weight]
301.38 |
Chemical Properties | Back Directory | [Melting point ]
154-156 °C(lit.)
| [alpha ]
+118° (c 1.0, CH2Cl2) | [Boiling point ]
457.1±30.0 °C(Predicted) | [density ]
1.23±0.1 g/cm3(Predicted) | [refractive index ]
118 ° (C=1, CH2Cl2) | [storage temp. ]
Refrigerator | [form ]
crystal | [pka]
3.78±0.70(Predicted) | [color ]
white | [optical activity]
[α]20/D +118°, c = 0.7 in methylene chloride |
Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals. |
Questions And Answer | Back Directory | [Reaction]
- Ligand for enantioselective nitrone cycloaddition to α,β-unsaturated 2-acyl imidazoles.
- Highly efficient catalytic enantioselective Mannich reaction of malonates with N-tert-butoxycarbonyl imines.
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