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ChemicalBook--->CAS DataBase List--->12176-31-7

12176-31-7

12176-31-7 Structure

12176-31-7 Structure
IdentificationBack Directory
[Name]

ETA-BENZENE(ETA-CYCLOPENTADIENYL)IRON HEXAFLUOROPHOSPHATE
[CAS]

12176-31-7
[Synonyms]

BENZENECYCLOPENTADIENYLIRON(II) HEXAFLU&
benzeneethacyclopentadienylironhexaflurophosphate
ETA-BENZENE(ETA-CYCLOPENTADIENYL)IRON HEXAFLUOROPHOSPHATE
η-Benzene(η-cyclopentadienyl)iron(II) Hexafluorophosphate
etha-Benzene(etha-cyclopentadienyl)iron Hexaflurophosphate
(η6-Benzene)(η5-cyclopentadienyl)iron(Ⅱ) Hexafluorophosphate
eta-Benzene(eta-cyclopentadienyl)iron(II) Hexafluorophosphate
[Molecular Formula]

C11H11F6FeP 5*
[MDL Number]

MFCD01631295
[MOL File]

12176-31-7.mol
[Molecular Weight]

344.01
Chemical PropertiesBack Directory
[Melting point ]

268 °C (dec.)(lit.)
[form ]

solid
[color ]

yellow
[Water Solubility ]

insol H2O, Et2O, THF; sol acetone, MeCN; mod sol CH2Cl2.
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Nitroxide-mediated photochemical-living radical polymerization reactions
  • Assembly of complex photonic crystals
  • Preparation of cyclopentadien-iron-biphenyl hexafluorophosphate ([Cp-Fe-biphenyl]+PF6-) for cationic photopolymerization of epoxy systems

Reactant for:
  • LIgand exchange reactions
  • Solid-state synthesis of carbon nanostructures
[reaction suitability]

reagent type: catalyst
core: iron
[Precautions]

[(C6H6)FeCp]PF6 is air stable. No special storage requirements are indicated. Its toxicity is unreported, but is probably low to moderate.
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