| Identification | Back Directory | [Name]
DI-N-BUTYLMAGNESIUM | [CAS]
1191-47-5 | [Synonyms]
nesium soL
DIBUTYLMAGNESIUM
dibutyl-magnesiu
MAGNESIUM DIBUTYL
DI-N-BUTYLMAGNESIUM
DI-N-BUTYLMAGNESIUM
Dibutylmagnesium solution
dibutyl magnesium solution
di-n-butylmagnesium solution
DIBUTYL MAGNESIUM SOLUTION APPROX. 0.75
Di-n-butylmagnesium solution 1.0 in heptane
DIBUTYLMAGNESIUM, 1.0M SOLUTION IN HEPTA NE
DIBUTYL MAGNESIUM SOLUTION, ~1 M IN HEPT ANE
Di-n-butylmagnesium, 0.5M solution in heptane
Di-n-butylMagnesiuM solution 1.0 M in heptane
Di-n-butylmagnesium, 1.0M solution in hexane, J&KSeal
Di-n-butylmagnesium0.5M solution in heptaneAcroSeal§3
Di-n-butylmagnesium solution 1 M in ether and hexanes
Di-n-butylMagnesiuM, 0.5M solution in heptane, SpcSeal
Di-n-butylmagnesium, 0.5M solution in heptane, AcroSeal
Di-n-butylMagnesiuM, 0.5M solution in heptane, AcroSeal 100ML
Di-n-butylMagnesiuM solution, 1.0 M solution in heptane, SpcSeal | [EINECS(EC#)]
214-736-7 | [Molecular Formula]
C8H18Mg | [MDL Number]
MFCD00015225 | [MOL File]
1191-47-5.mol | [Molecular Weight]
138.53 |
| Hazard Information | Back Directory | [Chemical Properties]
The pure substance is a waxy solid. Commercially, it is marketed as solution in?heptane. Di-n-butylmagnesium solution is a useful reagent for the synthesis of organomagnesium compounds. | [Uses]
Electrochemically inactive [Mg2(μ-Cl)3?6THF][C2H5AlCl3] crystal may be obtained from an electrolyte composed of Di-n-butylmagnesium and ethylaluminum dichloride. Di-n-butylmagnesium may be used in the carbon metallation of α-olefins. A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS2 or WO2Cl2. Interaction of lithium alkoxide with di-n-butylmagnesium was investigated. | [Application]
Di-n-butylmagnesium solution can be used as a reagent for the deprotection of aromatic and aliphatic benzyl thioethers to synthesize corresponding benzylthiols in the presence of titanocene dichloride. It can also be used as a catalyst to synthesize enantioenriched nitrogen-containing heterocyclic derivatives by the asymmetric ring-opening reaction of aziridines with substituted tetrazoles in the presence of chiral ligand. | [General Description]
Contains up to 1 wt. % Triethylaluminum as a viscosity reducer |
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