Identification | Back Directory | [Name]
GLYCIDYL ACRYLATE | [CAS]
106-90-1 | [Synonyms]
M 581 SR 378 glycidyl NSC 24151 NSC 67196 glycidylpropenate GLYCIDYL ACRYLATE Glycidyl propenate acrylatedeglycidyle GLYCIDYL PROPENOATE Acrylic acid glycidyl 2 3-EPOXYPROPYL ACRYLATE acrylicacidglycidylester 2-Oxiranylmethyl acrylate 2,3-Epoxypropanol acrylate 2,3-epoxy-1-propanoacrylate Acrylic acid glycidyl ester glycidylesterkyselinyakrylove Glycidylester kyseliny akrylove oxiran-2-ylmethyl prop-2-enoate 2,3-EPOXYPROPYL-ACRYLICACIDESTER 1-Propanol, 2,3-epoxy-, acrylate ACRYLIC ACID 2,3-EPOXYPROPYL ESTER 2-propenoicacid,oxiranylmethylester Propenoic acid oxiranylmethyl ester glycidylesterkyselinyakrylove(czech) 2-Propenoic acid,2-oxiranylMethyl ester Methacyclic acid, 2,3-epoxypropyl ester Glycidyl Acrylate (stabilized with MEHQ) 2,3-epoxypropyl acrylate glycidyl acrylate | [EINECS(EC#)]
203-440-3 | [Molecular Formula]
C6H8O3 | [MDL Number]
MFCD00005138 | [MOL File]
106-90-1.mol | [Molecular Weight]
128.13 |
Chemical Properties | Back Directory | [Appearance]
amber liquid | [Melting point ]
-42 °C | [Boiling point ]
60°C 16mm | [density ]
1.1163 g/cm3 | [refractive index ]
1.4508 (589.3 nm 20℃) | [Fp ]
61°C(lit.) | [storage temp. ]
-20°C Freezer | [solubility ]
Chloroform (Sparingly), Methanol (Slightly) | [form ]
clear liquid | [color ]
Colorless to Light orange to Yellow | [Stability:]
Stability Combustible. Incompatible with strong oxidizing agents. May be prone to polymerization. | [EPA Substance Registry System]
Glycidyl acrylate (106-90-1) |
Hazard Information | Back Directory | [Chemical Properties]
amber liquid | [Uses]
Labelled Glycidyl | [General Description]
Light amber liquid. | [Air & Water Reactions]
Water soluble. | [Reactivity Profile]
GLYCIDYL ACRYLATE may be sensitive to polymerizing conditions and/or catalysts. GLYCIDYL ACRYLATE will react with oxidizers. | [Health Hazard]
TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Fire Hazard]
GLYCIDYL ACRYLATE is combustible. | [Hazard]
Irritant to skin and eyes | [Description]
Glycidyl acrylate (GA) is a monomer that polymerizes in the presence of a free-radical initiator to form polyacrylic acid. This compound is used as a cross-linking agent for coatings, adhesives, and sealing compounds. GA is an excellent starting material for the preparation of cationic polymers with high reactivity and good stability. It has been used as a control agent in the synthesis of polycarboxylic acids and fatty acids. The hydroxyl group on this molecule allows it to be used as a water-repellent coating or sealant.
| [Application]
Glycidyl acrylate is used as monomer (polymers for adhesives and coatings), crosslinking agent (polymers of trialkyltin esters), and epoxy resin diluent. | [Toxicology]
For Glycidyl acrylate (GA), LD50 values of 210 mg/kg bw and 150 mg/kg bw were reported in 2 studies in rats and a LD50 of 89 mg/kg bw was reported in rabbits (NLM). Glycidyl methacrylate (GMA) is classified as hazardous as a Category 1B substance with risk phrase 'May damage fertility' in HCIS (Safe Work Australia). The available data for GMA are consistent with this classification. Given the structural similarity and common metabolite (glycidol), this classification is also warranted for GA. |
Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
23/24/25-34-43 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
2810 | [RTECS ]
AS9275000 | [HS Code ]
2916.12.5050 | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Safety Profile]
A poison by ingestion,
inhalation, and skin contact. Mutation data
reported. A skin and severe eye irritant.
Flammable liquid when exposed to heat or
flame. Can react vigorously with oxidmers.
To fight fire, use foam, dry chemical, CO2.
When heated to decomposition it emits
acrid smoke and fumes. See also ESTERS. | [Hazardous Substances Data]
106-90-1(Hazardous Substances Data) |
|
|